𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Hybrid single-electron-transfer-SN2 reactions

✍ Scribed by Bordwell, F. G.; Harrelson, John A.

Book ID
126158561
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
238 KB
Volume
109
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Single Electron Transfer vs. SN2 Reactio
Single Electron Transfer vs. SN2 Reaction
✍ MarciaΒ E.Β Van Loo; Johan Lugtenburg; Jan Cornelisse πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 251 KB

Reaction of the 5-hydroacenaphthylene anion with benzyl halides proceeds at carbon atom 1 as well as at carbon atom 2a, in the latter case creating a quaternary centre. The hardness-softness of the electrophiles was shown to play only a minor role in determining the regioselectivity of the reaction

Electron-transfer-coupled SN2 reaction m
Electron-transfer-coupled SN2 reaction mechanism in the gas phase
✍ Xinyu Song πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier 🌐 English βš– 442 KB

This calculation introduces a promising way to catalyze gas-phase S N 2 reactions at a unimolecular level by using an excess electron (EE) as an ''electron solvent''. The EE participation leads to very favorable energetics for the reaction, by neutralizing the created positive charge as the reaction