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Hybrid Open Networks (MIL 16): Synthesis, Crystal Structure, and Ferrimagnetism of Co 4 (OH) 2 (H 2 O) 2 (C 4 H 4 O 4 ) 3 ·2H 2 O, a New Layered Cobalt(II) Carboxylate with 14-Membered Ring Channels

✍ Scribed by Livage, Carine; Egger, Chrystelle; Férey, Gérard


Book ID
121368542
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
211 KB
Volume
11
Category
Article
ISSN
0897-4756

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A new hybrid organic+inorganic three-dimensional compound, [Co 4 (OH) has been synthesized via hydrothermal reactions and characterized by single-crystal X-ray di4raction, infrared spectroscopy, thermogravimetric analysis, and magnetic techniques. Compound 1 crystallizes in the monoclinic space gro