Poly(butyl acrylate-g-styrene) graft copolymers were prepared by free-radical polymerization using a polystyrene macromonomer carrying a methacryloyloxy group at the chain end and they were characterized by size-exclusion chromatography, and Fourier transform infrared spectroscopy. Glass transition
Humidity sensing properties of the vinylpyridine–butyl acrylate–styrene copolymers
✍ Scribed by Shuizhu Wu; Yinlan Zhu; Fengxian Li; Jiarui Shen
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 118 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
In this article, the humidity sensors based on the vinylpyridine (VP)-butyl acrylate (BA)-styrene (St) copolymers are developed. The influencing factors of the copolymer's humidity sensing properties, such as the mol percentage of the fed monomers and the quaternization reagent ratio (namely, dibromobutane : butyl bromide ratio), are studied, and the long-term stability of the copolymers is investigated as well. The results show that as the content of BA increases and the content of St decreases, the copolymer's hysteresis and response time decreases, and with the increasing of the quaternization reagent ratio, the copolymer's hysteresis and response time decreases. Also, the sensors based on the copolymers show 2-3% RH reproducibility under various long-term test conditions. These results demonstrate an overall excellent performance in the reproducibility and long-term stability.
📜 SIMILAR VOLUMES
Atom transfer radical polymerization conditions with copper(I) bromide/pentamethyldiethylenetriamine (CuBr/PMDETA) as the catalyst system were employed for the polymerization of tert-butyl acrylate, methyl acrylate, and styrene to generate welldefined homopolymers, diblock copolymers, and triblock c