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Hula-Twist: A Stereoselective and Regioselective Photoisomerization Reaction Mechanism

โœ Scribed by Robert S. H. Liu; Lan-Ying Yang; Cheryl Hirata; Jin Liu; Tong-Ing Ho

Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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Recently, the case for medium-dependent photoisomerization from the S 1 state was made; [1] it was argued that the onebond-flip (OBF) process (or torsional relaxation) [2] dominates in solutions, but this volume-demanding process is unlikely in confined media. Instead, a volume-conserving reaction m