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HRh(CO)(PPh3)3 encapsulated mesopores of hexagonal mesoporous silica (HMS) acting as nanophase reactors for effective catalytic hydroformylation of olefins

โœ Scribed by N. Sudheesh; Sumeet K. Sharma; Ram S. Shukla; Raksh V. Jasra


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
758 KB
Volume
296
Category
Article
ISSN
1381-1169

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Investigations on the kinetics of hydrof
โœ N. Sudheesh; Sumeet K. Sharma; Ram S. Shukla; Raksh V. Jasra ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 502 KB

Kinetics of HRh(CO)(PPh 3 ) 3 encapsulated in hexagonal mesoporous silica has been investigated for the heterogeneous catalyzed hydroformylation of 1-hexene. The rates of hydroformylation of C 5 -C 12 alkenes, determined under identical conditions, indicated a decreasing trend on increasing the chai