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HPLC optical resolution of tricarbonyl(2,3-dihydrotropone)iron and its absolute configuration

โœ Scribed by Hideo Sotokawa; Akio Tajiri; Noboru Morita; Chizuko Kabuto; Masahiro Hatano; Toyonobu Asao


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
237 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Dedicated to Professor George BLichi on the occasion of his 65th birthday Summary: Optical resolution of (?)-tricarbonyl(2,3-dihydrotropone)iron was carried out, and the absolute configuration was determined by X-ray diffraction and CD spectroscopic studies.


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Enantiomers of 3-methylazetidin-2-one -(3R)-(+)-and (3S)-(-)-1 and of 3-amino-2methylpropionic acid -(2R)-(-)-and (2S)-(+)-2 were obtained from corresponding diastereomers of methyl (ty.S)-N-t~-methylbenzyl-3-amino-2-methylpropionate 3A,B which had been separated by recrystallization of their salts