𝔖 Bobbio Scriptorium
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How ‘Soft’ are ‘Soft ionization methods’?

✍ Scribed by D. Renner; G. Spiteller


Book ID
101759124
Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
341 KB
Volume
13
Category
Article
ISSN
1076-5174

No coin nor oath required. For personal study only.

✦ Synopsis


Liquid compounds containing no acidic hydrogens produce [MI+' ions of high energy in low yield upon particle bombardment. The molecular ions undergo fragmentation in a similar way, as if the compounds were ionized by electron impact. 'Soft ionization' spectra produced by fast atom bombardment mass spectrometry and liquid secondary ion mass spectrometry are actually spectra obtained from ions already existing in the matrix. The main feature of the bombarding particles is to sputter the ions, not to ionize neutral molecules.


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