How High is the Barrier for the Valence Isomerization of Cyclobutadiene?
β Scribed by Prof. Dr. Gunther Maier; Dipl.-Chem. Reinhard Wolf; Dr. Hans-Otto Kalinowski
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 420 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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An ab initio computational study was carried out on the ground-and transition-state structures for the rotational isomerization of the allyl and the 1-cyano, 1-hydroxy-and 1-cyano-1-hydroxyallyl radical systems in an attempt to gain an understanding of the factors affecting the relative energy barri