𝔖 Bobbio Scriptorium
✦   LIBER   ✦

How facile is CH activation?—A semi-empirical study

✍ Scribed by Carlito B. Lebrilla; Wilhelm F. Maier

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
439 KB
Volume
105
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Low activation barriers arc predicted for all atoms uith p electrons in a_ereement with quahbtivc MO argumenls and experimental results

📜 SIMILAR VOLUMES

Supercritical fluid impregnation of poly
Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η5-C5Me5)Ir(CO)2 and the effect on CH activation
✍ Andrew I. Cooper; Sergei G. Kazarian; Martyn Poliakoff 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 588 KB

Polyethylene (PE) fdm is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp%(CO)z (Cp%$-CsMes) using supercritical CO, and subsequently saturated with HORe (RF= (CFs)zCH or (CFs)sC). At 200 K, the equilibrium between Cp\*Ir(CO)z and the