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How does magnetic field affect polymerization in supercritical fluids? Study of radical polymerization in supercritical CO2

✍ Scribed by Liu, Jun; Zhang, Rui; Li, Hongping; Han, Buxing; Liu, Zhimin; Jiang, Tao; He, Jun; Zhang, Xiaogang; Yang, Guanying

Book ID
115461046
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
150 KB
Volume
26
Category
Article
ISSN
1144-0546

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The free-radical polymerization of styrene has been studied in the homogeneous phase of supercritical (sc) CO 2 at 80 8C and pressures between 200 and 1 500 bar. 2,29-Azobisisobutyronitrile is used as initiator and CBr 4 as chain-transfer agent. The polymerization is monitored by means of online FT-