How Do Redox Groups Behave around a Rigi
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Abdou K. Diallo; Jean-Claude Daran; François Varret; Jaime Ruiz; Didier Astruc
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Article
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2009
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John Wiley and Sons
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English
⚖ 540 KB
## Abstract A new family of hexakis(ferrocenylethynyl)benzenes was synthesized by Negishi coupling from ethynylferrocenes and C~6~Br~6~ and can be reversibly oxidized to stable hexaferrocenium salts (see picture, Ar^F^=[3,5‐C~6~H~3~(CF~3~)~2~]). Their cyclic voltammograms show a single six‐electron