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HOTf-Catalyzed Rearrangement of Methylenecyclopropane Aryl and Alkyl Alcohols

โœ Scribed by Xiang-Ying Tang; Min Shi

Book ID
102176597
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
172 KB
Volume
2010
Category
Article
ISSN
1434-193X

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Palladium catalyzed arylation of N-alkyl
Palladium catalyzed arylation of N-alkyl O-allyl carbamates: Synthesis of cinnamyl alcohols via Heck arylation
โœ Keiji Ono; Keigo Fugami; Shuji Tanaka; Yoshinao Tamaru ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 269 KB

N-Alkyl O-cinnamyl carbamates (3) were prepared in good yields by palladium cat-'alyzed arylation of N-alkyl O-ally1 carbamak s (2) with aryl iodides. Heck type arylation of allylic alcohols with aromatic1 and IWemammatic halides2 is an efficient entry to the preparation of aromatic-substituted alky