Host (Nano Cage NaY)/Guest Mn(II), Co(II), Ni(II) and Cu(II) Complexes of N,N-Bis(3,5-Di-Tert-Butylsalicyidene)-2,2-Dimethyle-1,3-Diaminopropane: Synthesis and Catalyst Activity
β Scribed by Zendehdel, M.; Khanmohamadi, H.; Mokhtari, M.
- Book ID
- 123615882
- Publisher
- Chinese Electronic Periodical Services
- Year
- 2010
- Tongue
- English
- Weight
- 548 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0009-4536
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π SIMILAR VOLUMES
Transition metal (M = Mn(II), Co(II), Ni(II) and Cu(II)) complexes with tetradendate Schiff-base ligand; N,N -bis(salicylidene)phenylene-1,3-diamine, H 2 [sal-1,3-phen]; was entrapped in the nanocavity of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of bis(salicylaldiminato)me
of the pH and of the concentrations of buffers and acetonitrile. With the trans-14-macrocycle IV the kinetics are completely described by a second order rate constant: - For the other ligands, the same rate law is obtained from initial rates. Stability constants and standard potentials of the CuL'