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HONO formation as unknown radical source in photochemical smog chamber

✍ Scribed by Fumio Sakamaki; Hajime Akimoto

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 274 KB
Volume: 20
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550200204

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✦ Synopsis

Figure 1. The calculation results of the time profile of ozone formed in (a) NIES 1006 run and (b) UCR 178 run. 0; experimental results, curve A; calculation with no radical source, curve B; calculation with kld and [HONOlo = 0 ppb, curve C; calculation at the optimum condition (see Table ).

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Photoenhancement of the nitrous acid formation in the surface reaction of nitrogen dioxide and water vapor: Extra radical source in smog chamber experiments

✍ Hajime Akimoto; Hiroo Takagi; Fumio Sakamaki 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 637 KB

The surface reaction of NO2 and H 2 0 vapor to emit HONO into the gas phase was studied in the evacuable and bakeable photochemical chamber under the irradiation of UV-visible light ( 2 290 nm). Kinetic analysis of the NO, NOz, and HONO with the aid of computer modeling strongly suggested that the f