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Homopolymers of 5-chloro-8-quinolinyl acrylate and 5-chloro-8-quinolinyl methacrylate and their copolymers with acrylic and methacrylic acid

✍ Scribed by M. Bankova; Ts. Petrova; N. Manolova; I. Rashkov

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 799 KB
Volume: 32
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(95)00167-0

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✦ Synopsis

Optimal conditions for the preparation of 5-chloro-8-quinolinyl acrylate (AQ) and S-chloro-8-quinolinyl methacrylate (MQ) were found. Homopolymers were obtained by radical polymerization of AQ and MQ. Copolymers were obtained by copolymerization of AQ with acrylic acid (AA) and MQ with methacrylic acid (MA). The obtained monomers and polymers were characterized by spectroscopic methods (i.r., 'H and 13C-NMR), gel-permeation chromatography (GPC) and differential scanning calorimetry @SC). It was shown that the water-soluble copolymers of AA and AQ (AQ content 5 or 14mol%) form interpolymer complexes with poly(N-vinyl-2-pyrrolidone).

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