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Homolytic substitutions in indolinone nitroxide radicals—III: Reactions with terbutoxy and methyl radicals

✍ Scribed by L. Greci


Book ID
103401286
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
259 KB
Volume
38
Category
Article
ISSN
0040-4020

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Reactions of radicals with polymers—III.
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The kinetics of H abstraction by methyl and tert.butyl radicals from poly(p-tert.butyl styrene) (PTL3) films (5 × 10 3 mm thick) have been investigated at 298 K, both radicals being produced from the polymer by its exposure to short-wave u.v. radiation (2 = 254 nm) at pressures < 10 -4 Pa. Different