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Homolytic substitution at selenium: ring closure of ω-(benzylseleno)alkyl radicals

✍ Scribed by Lynda J. Benjamin; Carl H. Schiesser; Katarina Sutej

Book ID
104203906
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
758 KB
Volume
49
Category
Article
ISSN
0040-4020

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📜 SIMILAR VOLUMES

Rate coefficients for intramolecular hom
Rate coefficients for intramolecular homolytic substitution of oxyacyl radicals at selenium
✍ Heather M. Aitken; Sonia M. Horvat; Carl H. Schiesser; Ching Yeh Lin; Michelle L 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 365 KB

## Abstract Ab initio and density functional calculations predict that intramolecular homolytic substitution reactions of oxyacyl radicals at the selenium atom in ω‐alkylseleno‐substituted radicals proceed via mechanisms that do not involve hypervalent intermediates. When the leaving radical is __t