Homolytic alkylation of 2-methylquinoline with 18-crown-6
✍ Scribed by Yu. B. Zelechonok; V. V. Zorin; S. S. Zlotskii; D. L. Rakhmankulov
- Book ID
- 112355852
- Publisher
- Springer US
- Year
- 1985
- Tongue
- English
- Weight
- 58 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0009-3122
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 168 K Mean '(C±C) = 0.010 A Ê Disorder in main residue R factor = 0.060 wR factor = 0.107 Data-to-parameter ratio = 19.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
lsopropylidene malonate (2,2-dimethyl-4,6-dioxo-l,3-dioxane, Meldrum's acid) has a high acidity (pK1 = 4.97), a rigid cyclic structure and can undergo easy hydrolysis. It has become an attractive reagent in or anic synthesis.' For example, it can readily undergo Knoevena el conden~ation?'~ Michael a