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Homolytic 1,5-transfer of the Bu3Sn group from enoxy oxygen and allylic carbon to nitrogen

✍ Scribed by Sunggak Kim; Myung Suk Jung; Chang Ho Cho; Carl H Schiesser

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 75 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)02152-3

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✦ Synopsis

Homolytic 1,5-transfer of the Bu 3 Sn and Ph 3 Ge group from enoxy oxygen and allylic carbon to sulfonyl nitrogen were studied. We found that 1,5-Bu 3 Sn transfers from enoxy oxygen or allyl carbon to sulfonyl nitrogen occurred cleanly, whereas a reaction of a keto-aziridine with Ph 3 GeD under the radical conditions did not take place.

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