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Homolytic 1,2-elimination of hydrogen bromide

✍ Scribed by P.B.D. de la Mare; R.D. Wilson

Book ID: 104243127
Publisher: Elsevier Science
Year: 1974
Tongue: French
Weight: 102 KB
Volume: 15
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92006-4

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✦ Synopsis

Recently, it has been noted' that some autocatalysed brominations involving the formation of HDr may involve free-radical processes. The fact that adducts are formed acconpanying the rather colnplex course of bromination of cholest-5-e+3-one has led us to investigate the course of elimination from 5ar6&dibromocholestar+3-one (partial formula ?a) and ?,6a-dibromocholestan-3-one (partial formula lb).

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