Homologation of primary alcohols
โ Scribed by M.S. Scurrell
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 81 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0926-860X
No coin nor oath required. For personal study only.
โฆ Synopsis
N6
carried out by Catalytica and partners, Petro-Canada and Techmocisco Inc., a wholly owned subsidiary of Mitsubishi Oil Co. Catalytica feel that the key factor in the conversion is the generation of methyl bisuiphate, which under reaction conditions is less reactive than methane itself.
๐ SIMILAR VOLUMES
The reaction of benzo-l,3-dioxanes or benzo-l,3-oxathianes 1 [easily prepared from 2hydtoxy or 2-mercapto bonzylic alcohols (3 or 4, respectively) and carbonyl compounds] with an excess of lithium and a catalytic amount of DTBB (4.5 tool %) in THF at room temperature or -78\*(2 leads, after hydrolys