Homoleptic Organometallic Compounds of Zinc, Cadmium, and Mercury, Intramolecularly Stabilized by Amine Ligands

✍ Scribed by Herbert Schumann; Silke Freitag; Frank Girgsdies; Holger Hemling; Gabriele Kociok-Köhn

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 507 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199802)1998:2<245::aid-ejic245>3.0.co;2-t

✦ Synopsis

Homoleptic intramolecularly stabilized organozinc, -cad-(5). The crystal structures of Hg(C 6 H 4 CH 2 NEt 2 -2) 2 (1c), [M(CH 2 CH 2 CH 2 ) 2 NMe] 2 [M = Zn (4a), Hg (4c)], and of mium, and -mercury compounds MR 2 , with R bearing an amino function, have been synthesized from the correspond-M(CH 2 CH 2 CH 2 NC 5 H 10 ) 2 [M = Zn (5a), Cd (5b)] have been determined by X-ray diffraction. 4a and 4c form dimers with ing metal dichlorides MCl 2 and the lithium salts LiC 6 H 4 CH 2 -NEt 2 -2 (1), LiC 6 H 3 (CH 2 NMe 2 ) 2 -2,6 (2), LiC 6 H 3 (CH 2 NEt 2 ) 2 -an unusual coordination number (three) of the central metal. 2,6 (3), (LiCH 2 CH 2 CH 2 ) 2 NMe (4), and LiCH 2 CH 2 CH 2 NC 5 H 10