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Homoleptic Organometallic Anions of Ti, Zr, Hf, and Nb

✍ Scribed by Said El-Kurdi; Prof. Dr. Konrad Seppelt


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
262 KB
Volume
17
Category
Article
ISSN
0947-6539

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13C and 77Se NMR of some organometallic
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C and 77Se NMR was carried out on dicyclopentadienyl derivatives of Ti, Zr and W with selenium bonded directly to the metal. Although '"C NMR is not sensitive to different substitution, 77Se NMR is valuable and refiects the influence of the different organic substituents and the nature of the metals

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The standard molar enthalpies of sublimation of M(η 5 -C 5 H 5 )Cl 2 (M = Ti, V, Zr, Nb, Hf, and W) compounds, at 298.15 K, were determined by the Knudsen effusion method to be: 124.4±2.9 kJmol -1 (M = Ti), 108.5±4.6 kJmol -1 (M =