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Homogeneous palladium-catalysed arylation of activated alkenes with aryl chlorides

โœ Scribed by Alwyn Spencer


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
364 KB
Volume
270
Category
Article
ISSN
0022-328X

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## Bridgehead acid chlorides la and lb react with activated alkenes 2 in the presence of a catalytic amount of palladium and 1 equiv of a tertiary amine. The reaction proceeds regio-and stereoselectively at the terminal carbon atoms to yield acylated alkenes 3 with E-configuration. Acylpalladium c