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Homogeneous hydrogenation of the carbonyl group of 3,7-dimethylocta-2,6-dienal using RuHCl(PPh3)3—HCl catalyst

✍ Scribed by Kazuhiko Hotta


Publisher
Elsevier Science
Year
1985
Weight
182 KB
Volume
29
Category
Article
ISSN
0304-5102

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The regioselective hydrogenation of some imines to the corresponding amines is efficiently catalyzed by [Ir(COD)(PPh 3 ) 2 ]PF 6 (1) and [Rh(COD)(PPh 3 ) 2 ]PF 6 (2) at 60 • C and 200 psi of H 2 . The kinetics of the hydrogenation of N-(␤-naphthyl methylene) aniline (N␤NA) with [Ir(COD)(PPh 3 ) 2 ]P