The regioselective hydrogenation of some imines to the corresponding amines is efficiently catalyzed by [Ir(COD)(PPh 3 ) 2 ]PF 6 (1) and [Rh(COD)(PPh 3 ) 2 ]PF 6 (2) at 60 • C and 200 psi of H 2 . The kinetics of the hydrogenation of N-(-naphthyl methylene) aniline (NNA) with [Ir(COD)(PPh 3 ) 2 ]P
✦ LIBER ✦
Homogeneous Hydrogenation of Benzo[ b ]thiophene by Use of Rhodium and Iridium Complexes as the Catalyst Precursors: Kinetic and Mechanistic Aspects †
✍ Scribed by Herrera, Verónica; Fuentes, Alberto; Rosales, Merlín; Sánchez-Delgado, Roberto A.; Bianchini, Claudio; Meli, Andrea; Vizza, Francesco
- Book ID
- 126160367
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 176 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0276-7333
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