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Homogeneous Crystallization of Poly(Ethylene Oxide) Confined to Droplets: The Dependence of the Crystal Nucleation Rate on Length Scale and Temperature

✍ Scribed by Massa, Michael V.; Dalnoki-Veress, Kari


Book ID
125850350
Publisher
The American Physical Society
Year
2004
Tongue
English
Weight
253 KB
Volume
92
Category
Article
ISSN
0031-9007

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The crystallization rates of fractions of poly(ethylene oxide) have been studied microseopically and dilatometrically. Nucleation theory has been adapted to take account of the finite molecular weight and the molecular weight distribution of the fractions. It is found that the free energy of formati