Homogeneous Controlled Free Radical Polymerization in Aqueous Media
β Scribed by Andrew B. Lowe; Charles L. McCormick
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 51 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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The free-radical polymerization of styrene has been studied in the homogeneous phase of supercritical (sc) CO 2 at 80 8C and pressures between 200 and 1 500 bar. 2,29-Azobisisobutyronitrile is used as initiator and CBr 4 as chain-transfer agent. The polymerization is monitored by means of online FT-
## Abstract The free radical polymerization kinetics of the isomer sodium salts of __o__β and __p__βmethacryloylaminophenylarsonate in aqueous solution have been studied using a dilatometric method. The polymerizations, initiated with potassium persulfate, were carried out at a constant monomer ini