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Homogeneous catalyzed reduction of nitrocompounds: II. Hydrogenation to oximes

✍ Scribed by J.F. Knifton


Book ID
113174891
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
788 KB
Volume
33
Category
Article
ISSN
0021-9517

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Sodium arenetellurolate-catalyzed reduct
✍ Kouichi Ohe; Sakae Uemura πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 408 KB

Treatment of aliphatic nitro compounds with NaBH4 in alkaline ethanol in the presence of a catalytic amount o f diaryl ditelluride at 25Β°C for 5-20 h produces the Corresponding oximes, generally as a mixture of EIZ isomers, in fair to good yields. Arenetellurolate anion (ArTe -) generuted in situ is