Homogeneous catalytic reactions of methanol with carbon monoxide
โ Scribed by Denis Forster; T.C. Singleton
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 966 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0304-5102
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๐ SIMILAR VOLUMES
The reagent hydrosilane/carbon monoxide opens up new possibilities for organic synthesis. Four cases will be discussed: 1. The reaction of olefins with hydrosilane (trialkylsilane) and carbon monoxide in the presence of Co, Ru, and Rh complexes leads to enol silyl ethers having one more carbon atom
It has been known that a methanolic solution of mercuric acetate absorbs carbon monoxide to form carbomethoxymercuric acetate 1) . Recently,') the reaction of carbomethoxymercuric acetate with primary and secondary amines was reported, in which the corresponding urethane was formed. Thallium (III)