The oxidative carbonylation of methane to acetic acid was investigated using Pt(II) cations as the catalyst and sulfuric acid as the solvent. The reactions were carried out at 180 β’ C in a sealed batch reactor containing either fuming or concentrated (96 wt%) sulfuric acid (3 ml) and PtCl 2 (20 mM)
Homogeneous, catalytic, oxidative coupling of methane to acetic acid in one step
β Scribed by Roy A. Periana; Oleg Mironov; Doug Taube; Gaurav Bhalla; C. J. Jones
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 386 KB
- Volume
- 32
- Category
- Article
- ISSN
- 1022-5528
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## Abstract Recent results on surface reaction steps in the oxidative coupling of methane (OCM) obtained from (1) transient experiments and (2) a microkinetic analysis are summarized. The interaction of methane and oxygen with MgO and Sm~2~O~3~ surfaces was investigated by applying H/Dβ and oxygenβ
Oxidation of methane was studied for a number of oxides containing bismuth viz. Ba&aBi06, Ba,\_,La,BiO, (0 s x 5 0.7), Y0,5Bi1.603 and Bi20\* These oxides were selected in order to determine the influence of (a) oxidation state and structural environment of bismuth in an oxide lattice and (b) revers