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Homogeneous catalysis on metal clusters. The isomerization and selective hydrogenation of dienes, alkenes, and alkynes in the presence of [(?-C5H5)NiOs3(�-H)3(CO)9] and [(?-C5H5)NiOs3(�-H)3(CO)8L][L = PPh2H or P(C6H4Me-o)3]. Spectroscopic identification of the reaction intermediates and X-ray structure of [Os3(�-H)(CO)9(MeCCHCMe)]

✍ Scribed by Castiglioni, Mario; Giordano, Roberto; Sappa, Enrico; Tiripicchio, Antonio; Camellini, Marisa Tiripicchio

Book ID: 119975149
Publisher: The Royal Society of Chemistry
Year: 1986
Tongue: English
Weight: 879 KB
Volume: 1
Category: Article
ISSN: 1472-7773
DOI: 10.1039/DT9860000023

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