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Homogeneous Catalysis of the Hydrogenation of Olefinic Compounds by Ruthenium(II) Chloride1

โœ Scribed by Halpern, Jack; Harrod, John F.; James, Brian R.


Book ID
111901577
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
696 KB
Volume
88
Category
Article
ISSN
0002-7863

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Homogeneous catalytic transfer-hydrogena
โœ Yoel Sasson; Jochanan Blum ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 185 KB

Dichlorotris(triphenylphosphine)ruthenium (II), RuC12(PPh3)3, is well known for its ability to catalyze hydrogen transfer in several organic reactions l-10 . We now wish to report the application of this effect to the selective transfer-hydrogenation of a&unsaturated carbonyl compounds. A mixture of