Homogeneous catalysis of Friedel-Crafts-type reactions by arene-Group VIB tricarbonyls

Introduction of an arylthio(trimethylsil

Introduction of an arylthio(trimethylsilyl)methyl group into arenes by friedel-crafts reaction: synthesis of arylmethyltrimethylsilanes

✍ Hiroyuki Ishibashi; Hiroshi Nakatani; Yoshizumi Umei; Masazumi Ikeda 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 111 KB

Friedel-Crafts reactions of [arylthio(chloro)methyl]trimethylsilanes (ti,&) with arenes gave [aryl(arylthio)methyl]trimethylsilanes (a,b>, which were converted into arylmethyltrimethylsilanes (3) by reduction with Raney nickel. Arylmethyltrimethylsilanes (3) are versatile intermediates in organic sy