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Homogeneous catalysis of arene hydrogenation by cationic rhodium arene complexes

✍ Scribed by Landis, Clark R.; Halpern, Jack


Book ID
126162566
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
375 KB
Volume
2
Category
Article
ISSN
0276-7333

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Effect of CO on the Oxidative Addition o
✍ Michael Montag; Irena Efremenko; Revital Cohen; Lindaβ€…J.β€…W. Shimon; Gregory Leit πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 782 KB

## Abstract Sequential addition of CO molecules to cationic aryl–hydrido Rh^III^ complexes of phosphine‐based (PCP) pincer ligands was found to lead first to Cο£ΏH reductive elimination and then to Cο£ΏH oxidative addition, thereby demonstrating a dual role of CO. DFT calculations indicate that the oxi