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Homogeneous catalysis by metal clusters. 2. Tetranuclear osmium complexes as catalyst precursors in the hydrogenation of styrene

✍ Scribed by Sanchez-Delgado, Roberto A.; Andriollo, Antida; Puga, Jose; Martin, Gonzalo


Book ID
125976894
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
802 KB
Volume
26
Category
Article
ISSN
0020-1669

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The regioselective hydrogenation of some imines to the corresponding amines is efficiently catalyzed by [Ir(COD)(PPh 3 ) 2 ]PF 6 (1) and [Rh(COD)(PPh 3 ) 2 ]PF 6 (2) at 60 β€’ C and 200 psi of H 2 . The kinetics of the hydrogenation of N-(␀-naphthyl methylene) aniline (N␀NA) with [Ir(COD)(PPh 3 ) 2 ]P