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Homogeneous and Polymer-Supported Catalysts in the Oxidation of α-Pinene with Oxygen

✍ Scribed by S. Yu. Men’shikov; M. Yu. Sennikov; Yu. V. Romanova; N. S. Sycheva; A. A. Ostroushko

Book ID
111609272
Publisher
SP MAIK Nauka/Interperiodica
Year
2004
Tongue
English
Weight
83 KB
Volume
40
Category
Article
ISSN
1070-4280

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✍ Charles W. Jefford; André F. Boschung; Robert M. Moriarty; Christian G. Rimbault 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 German ⚖ 642 KB

## Abstract The reaction of photogenerated singlet oxygen with α‐ and β‐pinenes has been carefully re‐examined. α‐Pinene almost exclusively (99.3% yield) furnishes __trans__‐3‐hydroperoxy‐pin2(10)‐ene. However, detectable amounts of the three other possible products are also found, viz., __cis__‐3‐