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Homogeneous activation of the CH bond in formates. Decarbonylation of formates to alcohols

✍ Scribed by Gérard Jenner; El Mostafa Nahmed; Hans Leismann


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
493 KB
Volume
387
Category
Article
ISSN
0022-328X

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An experimental determination of the hea
✍ Randall S. Urdahl; Yihan Bao; William M. Jackson 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 337 KB

The rotational cutoff levels of C,( B' 'Z:, u" = 1,2), produced in the multiphoton dissociation of jet-cooled acetylene at 193 nm, have been measured using laser-induced fluorescence. This data is used to calculate the values AHf,,(C2) = 194.8iO.5 kcal/ mol and D,(CC-H) = 112.0 kO.8 kcal/mol, in exc