Homocoupling of Aryl Iodides and Bromides Using a Palladium/Indium Bimetallic System.
β Scribed by Yu Mi Chang; Seung Hwan Lee; Min Young Cho; Byung Woo Yoo; Hak June Rhee; Sang Ho Lee; Cheol Min Yoon
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 19 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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Pd(PΓOΓP)(Ar)] complexes with ligands that have wide bite angles are active catalysts for the coupling of aniline derivatives with aryl triflates. Kinetic studies show that for these systems a fast equilibrium that involves coordination of the amine precedes the deprotonation, which is the rate-limi