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Homo- and Heteropolynuclear Platinum Complexes Stabilized by Dimethylpyrazolato and Alkynyl Bridging Ligands: Synthesis, Structures, and Luminescence

✍ Scribed by Juan Forniés; Sara Fuertes; Antonio Martín; Violeta Sicilia; Elena Lalinde; M. Teresa Moreno

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
426 KB
Volume
12
Category
Article
ISSN
0947-6539

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## Abstract Six novel Pt–Rh dinuclear complexes (1–6), [PtRh(PVM)~2~(NH~3~)~2~Cl~3~]·4H~2~O (1, PVM = __t__BuCONH^–^), [PtRh(PVM)~2~(en)Cl~3~]·3H~2~O (2, en = ethylenediamine), [PtRh(PVM)~2~(NH~2~CH~3~)~2~Cl~3~]·3H~2~O (3), [PtRh(PVM)~2~(NH~2~__t__Bu)~2~Cl~3~]·3H~2~O (4), [PtRh(TCM)~2~(NH~3~)~2~Cl~