𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Homo- and copolymerization with a highly active Ziegler–Natta catalyst

✍ Scribed by L. L. Böhm

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
507 KB
Volume
29
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The polymerization of ethylene with a hi
The polymerization of ethylene with a highly active Ziegler-Natta catalyst
✍ A.E. Yildirim 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 345 KB

A soluble ethylene catalyst were obtained by mixing a methylene dichloride solution of dichlorobislT-cyclopentadienyl) titanium (Cp2TiCI2) with a heptane solution of ethylaluminium sesquichloride (AlzEt3C13) or of diethylaluminium chloride {AIEt2CI). Ethylene was polymerized using these catalysts; t

Copolymerization with Ziegler-Natta cata
Copolymerization with Ziegler-Natta catalysts—IV. A possible kinetic scheme
✍ I.H. Anderson; G.M. Burnett; W.C. Geddes 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 289 KB

AbstractmThe concept of localized concentrations of monomer adsorbed on a catalytic surface is applied to a kinetic scheme for copolymerization by Ziegler-Natta catalysts. The equations derived are compared with those of Valvassori's approach and with other experimental results.

Highly active magnesium chloride support
Highly active magnesium chloride supported Ziegler-Natta catalysts with controlled morphology
✍ Madalena C. Forte; Fernanda M.B. Coutinho 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 792 KB

## Ah&met-Polymerizations of propylene were carried out by using the catalyst system MgCl,~ID~TiCl,-AlEt,.ED, where ID (internal donor) was an organic diester and ED (external donor) was a silane. The effect of preparation conditions on the chemical composition and morphology of the supports and c

Electrochemical synthesis of titanium-ba
Electrochemical synthesis of titanium-based Ziegler-Natta catalysts and their potential application in ethylene homo- and copolymerization
✍ Jean-Michel Brusson; André Mortreux; Francis Petit; Karel Bujadoux; Benoit Lepre 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 863 KB

## Abstract Highly active Ziegler‐Natta catalysts have been synthesized using an electrochemical process in their preparation, with the aim of producing selectively titanium(III) species from TiCl~4~. The use of an undivided cell, an aluminium anode and a halogenated solvent (dichloromethane or 1,2