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Hollow fibre perovskite membranes for oxygen separation

✍ Scribed by T. Schiestel; M. Kilgus; S. Peter; K.J. Caspary; H. Wang; J. Caro


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
180 KB
Volume
258
Category
Article
ISSN
0376-7388

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✦ Synopsis


Perovskite hollow fibre membranes of the chemical composition BaZr x Co y Fe z O 3-Ξ΄ (BCFZ) have been developed using a phase inversion spinning process followed by sintering. The BCFZ hollow fibre membranes show an O 2 flux of 7.6 ml/min/cm 2 at 900 β€’ C which is the highest value so far known. From the Wagner theory it follows that the O 2 transport through thin walled perovskite hollow fibre membranes is controlled by both vacancy diffusion and interface reactions.


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Tantalum stabilized SrCoO3βˆ’Ξ΄ perovskite
✍ Xinzhi Chen; Liu Huang; Yanying Wei; Haihui Wang πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 English βš– 784 KB

The mixed ion and electron conducting oxides of SrCo 1-y Ta y O 3-Δ± (0 ≀ y ≀ 0.3) powders were prepared by solid state reaction. By doping 10 mol% of tantalum on the B-site of SrCoO 3 , the cubic perovskite structure of the SrCoO 3 is stable and a high oxygen permeation flux is achieved. The phase s