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Hollandite-type compounds K2Me(FeV)3.5O16 (Me  Co or Ni) with magnetic ordering

✍ Scribed by I. Jacyna-Onyszkiewicz; T. Mydlarz


Book ID
113322050
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
185 KB
Volume
160
Category
Article
ISSN
0304-8853

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.