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Hole diffusion-controlled geminate charge recombination dynamics in doped poly(N-vinylcarbazole) films by transient absorption spectroscopy

โœ Scribed by Kazuya Watanabe; Tsuyoshi Asahi; Hiroshi Masuhara


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
457 KB
Volume
233
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Charge recombination dynamics of photogenerated ionic species in poly(N-vinylcarbazole) films doped with an electron acceptor was investigated by transient absorption spectroscopy in the microsecond to millisecond time region. The absorption decay was independent of the concentration of the ionic species and approximately obeys a t -~/2 time dependence. The observed recombination process was well interpreted in terms of hole diffusion-controlled geminate recombination process.


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Combining the measurements of the picosecond transient absorption spectra and the transient dichroism sensitive to the charge shift reaction processes, photoinduced charge separation (CS), recombination (CR) and hole transfer (HT) processes in poly(N-vinylcarbazole) solid films doped with electron a