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“Hole-burning spectra”. A new method for obtaining fine structure in absorption spectra of organic molecules

✍ Scribed by B.M. Kharlamov; L.A. Bykovskaya; R.I. Personov

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
419 KB
Volume
50
Category
Article
ISSN
0009-2614

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✦ Synopsis

A new method is proposed for obtaining tine structure in broad-band absorption spectra of organic molecules in solid solutions at low temperature. This method is based on the laser burning of a series of narrow gaps in inhomogeneously broadened absorption spectra. A special spectral set-up has been developed for the measurement of the differential spectrum (a "hole-burning spectrum") of "burnt" and "unburnt" samples. As an example the hole-bulning spectrum of Zn-tetraphenylporphine in ethanol has been considered.

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