Hindered Rotation of tert-Butyl Groups in Radical Cations of Highly Substituted Alkenes
β Scribed by Dr. Horst Eierdanz; Siegfried Potthoff; Dr. Rudolf Bolze; Prof. Dr. Armin Berndt
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 219 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Hindered rotation in two __o__βsubstituted __N__,__N__βdimethylthiobenzamides was investigated by variable temperature ^1^H NMR spectroscopy. For one compound, the enthalpies and entropies of activation for (i) thioamide group rotation around the Arο£ΏC bond and (ii) dimethylamino group r
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