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Hindered rotation in the N(2,2,2-trichlorocarboethoxy)nortropanes. An NMR study

✍ Scribed by P. Scheiber

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 165 KB
Volume: 13
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270130302

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✦ Synopsis

Abstract

A rarely occurring type of hindered rotation was observed by ^1^H NMR in some N‒(2,2,2‒trichlorocarboethoxy)nortropanes. A complete lineshape analysis gave the activation energy E~a~ = 56.9 kJ mol^‒1^ for the rotation around the CH~2~OCO bond.

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