## Abstract The molecule __N__,__N__‐dimethylacetoacetamide, which is subject to a keto–enol equilibrium process in solution, also exhibits hindered rotation about the amido NC bond. The hindered rotation rates have been studied by lineshape fit methods of the nuclear magnetic resonance spectra. I
✦ LIBER ✦
Hindered Rotation about the CO Bond in Methoxy(methyl)carbene Ligands
✍ Scribed by Dr. C. G. Kreiter; Prof. Dr. E. O. Fischer
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 222 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy