𝔖 Bobbio Scriptorium
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Hindered Rotation about the CO Bond in Methoxy(methyl)carbene Ligands

✍ Scribed by Dr. C. G. Kreiter; Prof. Dr. E. O. Fischer


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
222 KB
Volume
8
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Hindered rotation about the amido NC bon
✍ R. F. Hobson; L. W. Reeves; R. C. Shaddick 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 424 KB

## Abstract The molecule __N__,__N__‐dimethylacetoacetamide, which is subject to a keto–enol equilibrium process in solution, also exhibits hindered rotation about the amido NC bond. The hindered rotation rates have been studied by lineshape fit methods of the nuclear magnetic resonance spectra. I

Reversible CH Bond Activation Reactions
✍ Mark J. Chilvers; Rodolphe F. R. Jazzar; Mary F. Mahon; Michael K. Whittlesey 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 2 views

## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy