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Hindered internal rotation of the methyl group by ESR

✍ Scribed by Kuang S Chen; Jay K Kochi

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
290 KB
Volume
23
Category
Article
ISSN
0009-2614

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✦ Synopsis

Selecrive line broadening of the ESR spectrum of u,adifIuoroethyi radial shows hindered internal rotation of tho methyl group, from which 3 barrier of 1.1 kul mole -' is obtained by !ineshape analysis.

πŸ“œ SIMILAR VOLUMES

The spectrum of rotating wavepackets of
The spectrum of rotating wavepackets of hindered methyl groups
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The wavefunction of a quantum system driven by a thermal environment localises when environmentally induced motion overtakes oscillations of the undriven system. The slowing down of the oscillations with increasing temperature is an important aspect of the transition from wave-lie to particle-like b