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Highly trans -Stereospecific Isoprene Polymerization by Neodymium Borohydrido Catalysts †

✍ Scribed by Bonnet, Fanny; Visseaux, Marc; Pereira, Angela; Barbier-Baudry, Denise

Book ID
120979493
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
180 KB
Volume
38
Category
Article
ISSN
0024-9297

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✍ Michael Terrier; Emilie Brulé; Marta J. Vitorino; Noureddine Ajellal; Carine Rob 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 193 KB

## Abstract A series of hybrid materials, bearing neodymium silylamide initiating groups, have been shown to mediate isoprene polymerization when combined with alkyl aluminum activators [methylaluminoxane, AlEt~2~Cl, Al(__i__Bu)~3~]. The surface species nature and relative distribution were correla